The key here that will catch the attention of college admissions offices is that you are working to help your family. If you are working full time during the week, working part time during the weekend is another thing to add to your resume. If you need to do this to help your family, that is admirable. If you get a second job for your resume, it is not better to have two jobs than one job. What is important is that you are working full time to help your family. You don't want to get worn out by working all weeke with no time off to relax.